Optical constants of liquid and solid methane

The optical constants n(sub r) + in(sub i) of liquid methane and phase 1 solid methane were determined over the entire spectral range by the use of various data sources published in the literature. Kramers-Kronig analyses were performed on the absorption spectra of liquid methane at the boiling point (111 K) and the melting point (90 K) and on the absorption spectra of phase 1 solid methane at the melting point and at 30 K. Measurements of the static dielectric constant at these temperatures and refractive indices determined over limited spectral ranges were used as constraints in the analyses. Applications of methane optical properties to studies of outer solar system bodies are described

Exploration of a Polarized Surface Bidirectional Reflectance Model Using the Ground-Based Multiangle Spectropolarimetric Imager

Accurate characterization of surface reflection is essential for retrieval of aerosols using downward-looking remote sensors. In this paper, observations from the Ground-based Multiangle SpectroPolarimetric Imager (GroundMSPI) are used to evaluate a surface polarized bidirectional reflectance distribution function (PBRDF) model. GroundMSPI is an eight-band spectropolarimetric camera mounted on a rotating gimbal to acquire pushbroom imagery of outdoor landscapes. The camera uses a very accurate photoelastic-modulator-based polarimetric imaging technique to acquire Stokes vector measurements in three of the instrument's bands (470, 660, and 865 nm). A description of the instrument is presented, and observations of selected targets within a scene acquired on 6 January 2010 are analyzed. Data collected during the course of the day as the Sun moved across the sky provided a range of illumination geometries that facilitated evaluation of the surface model, which is comprised of a volumetric reflection term represented by the modified Rahman-Pinty-Verstraete function plus a specular reflection term generated by a randomly oriented array of Fresnel-reflecting microfacets. While the model is fairly successful in predicting the polarized reflection from two grass targets in the scene, it does a poorer job for two manmade targets (a parking lot and a truck roof), possibly due to their greater degree of geometric organization. Several empirical adjustments to the model are explored and lead to improved fits to the data. For all targets, the data support the notion of spectral invariance in the angular shape of the unpolarized and polarized surface reflection. As noted by others, this behavior provides valuable constraints on the aerosol retrieval problem, and highlights the importance of multiangle observations.NASAJPLCenter for Space Researc

Forest structure and aboveground biomass in the southwestern United States from MODIS and MISR

Red band bidirectional reflectance factor data from the NASA MODerate resolution Imaging Spectroradiometer (MODIS) acquired over the southwestern United States were interpreted through a simple geometric–optical (GO) canopy reflectance model to provide maps of fractional crown cover (dimensionless), mean canopy height (m), and aboveground woody biomass (Mg ha−1) on a 250 m grid. Model adjustment was performed after dynamic injection of a background contribution predicted via the kernel weights of a bidirectional reflectance distribution function (BRDF) model. Accuracy was assessed with respect to similar maps obtained with data from the NASA Multiangle Imaging Spectroradiometer (MISR) and to contemporaneous US Forest Service (USFS) maps based partly on Forest Inventory and Analysis (FIA) data. MODIS and MISR retrievals of forest fractional cover and mean height both showed compatibility with the USFS maps, with MODIS mean absolute errors (MAE) of 0.09 and 8.4 m respectively, compared with MISR MAE of 0.10 and 2.2 m, respectively. The respective MAE for aboveground woody biomass was ~10 Mg ha−1, the same as that from MISR, although the MODIS retrievals showed a much weaker correlation, noting that these statistics do not represent evaluation with respect to ground survey data. Good height retrieval accuracies with respect to averages from high resolution discrete return lidar data and matches between mean crown aspect ratio and mean crown radius maps and known vegetation type distributions both support the contention that the GO model results are not spurious when adjusted against MISR bidirectional reflectance factor data. These results highlight an alternative to empirical methods for the exploitation of moderate resolution remote sensing data in the mapping of woody plant canopies and assessment of woody biomass loss and recovery from disturbance in the southwestern United States and in parts of the world where similar environmental conditions prevail

Low Temperature Opacities

Previous computations of low temperature Rosseland and Planck mean opacities from Alexander & Ferguson (1994) are updated and expanded. The new computations include a more complete equation of state with more grain species and updated optical constants. Grains are now explicitly included in thermal equilibrium in the equation of state calculation, which allows for a much wider range of grain compositions to be accurately included than was previously the case. The inclusion of high temperature condensates such as Al$_2$O$_3$ and CaTiO$_3$ significantly affects the total opacity over a narrow range of temperatures before the appearance of the first silicate grains. The new opacity tables are tabulated for temperatures ranging from 30000 K to 500 K with gas densities from 10$^{-4}$ g cm$^{-3}$ to 10$^{-19}$ g cm$^{-3}$. Comparisons with previous Rosseland mean opacity calculations are discussed. At high temperatures, the agreement with OPAL and Opacity Project is quite good. Comparisons at lower temperatures are more divergent as a result of differences in molecular and grain physics included in different calculations. The computation of Planck mean opacities performed with the opacity sampling method are shown to require a very large number of opacity sampling wavelength points; previously published results obtained with fewer wavelength points are shown to be significantly in error. Methods for requesting or obtaining the new tables are provided.Comment: 39 pages with 12 figures. To be published in ApJ, April 200

An Integrated Approach for Characterizing Aerosol Climate Impacts and Environmental Interactions

Aerosols exert myriad influences on the earth's environment and climate, and on human health. The complexity of aerosol-related processes requires that information gathered to improve our understanding of climate change must originate from multiple sources, and that effective strategies for data integration need to be established. While a vast array of observed and modeled data are becoming available, the aerosol research community currently lacks the necessary tools and infrastructure to reap maximum scientific benefit from these data. Spatial and temporal sampling differences among a diverse set of sensors, nonuniform data qualities, aerosol mesoscale variabilities, and difficulties in separating cloud effects are some of the challenges that need to be addressed. Maximizing the long-term benefit from these data also requires maintaining consistently well-understood accuracies as measurement approaches evolve and improve. Achieving a comprehensive understanding of how aerosol physical, chemical, and radiative processes impact the earth system can be achieved only through a multidisciplinary, inter-agency, and international initiative capable of dealing with these issues. A systematic approach, capitalizing on modern measurement and modeling techniques, geospatial statistics methodologies, and high-performance information technologies, can provide the necessary machinery to support this objective. We outline a framework for integrating and interpreting observations and models, and establishing an accurate, consistent, and cohesive long-term record, following a strategy whereby information and tools of progressively greater sophistication are incorporated as problems of increasing complexity are tackled. This concept is named the Progressive Aerosol Retrieval and Assimilation Global Observing Network (PARAGON). To encompass the breadth of the effort required, we present a set of recommendations dealing with data interoperability; measurement and model integration; multisensor synergy; data summarization and mining; model evaluation; calibration and validation; augmentation of surface and in situ measurements; advances in passive and active remote sensing; and design of satellite missions. Without an initiative of this nature, the scientific and policy communities will continue to struggle with understanding the quantitative impact of complex aerosol processes on regional and global climate change and air quality

Response to "Toward Unified Satellite Climatology of Aerosol Properties. 3. MODIS Versus MISR Versus AERONET"

A recent paper by Mishchenko et al. compares near-coincident MISR, MODIS, and AERONET aerosol optical depth (AOD) products, and reports much poorer agreement than that obtained by the instrument teams and others. We trace the reasons for the discrepancies primarily to differences in (1) the treatment of outliers, (2) the application of absolute vs. relative criteria for testing agreement, and (3) the ways in which seasonally varying spatial distributions of coincident retrievals are taken into account

MISR Multi-Angle Imaging SpectroRadiometer

This viewgraph presentation reviews the concept of the Multi-Angle Imaging SpectroRadiometer (MISR), a methodology to use the MISR to retrieve aerosols over water and land. The presentation shows some of the results of the use of the MISR in graphs and charts. Multi-angle remote sensing provides unique ways of retrieving aerosol properties over many surface types, including bright deserts which are major source regions

Use of Multiangle Satellite Observations to Retrieve Aerosol Properties and Ocean Color

A new technique is described for retrieving aerosol over ocean water and the associated ocean color using multiangle satellite observations. Unlike current satellite aerosol retrieval algorithms which only utilize observations at red wavelengths and longer, with the assumption that these wavelengths have a negligible ocean (water-leaving radiance), this new algorithm uses all available spectral bands and simultaneously retrieves both aerosol properties and the spectral ocean color. We show some results of case studies using MISR data, performed over different water conditions (coastal water, blooms, and open water)

Forest canopy height from the Multiangle Imaging SpectroRadiometer (MISR) assessed with high resolution discrete return lidar

In this study retrievals of forest canopy height were obtained through adjustment of a simple geometricoptical (GO) model against red band surface bidirectional reflectance estimates from NASA\u27s Multiangle Imaging SpectroRadiometer (MISR), mapped to a 250 m grid. The soil-understory background contribution was partly isolated prior to inversion using regression relationships with the isotropic, geometric, and volume scattering kernel weights of a Li-Ross kernel-driven bidirectional reflectance distribution function (BRDF) model. The height retrievals were assessed using discrete return lidar data acquired over sites in Colorado as part of the Cold Land Processes Experiment (CLPX) and used with fractional crown cover retrievals to obtain aboveground woody biomass estimates. For all model runs with reasonable backgrounds and initial b/r (vertical to horizontal crown radii) values \u3c2.0, root mean square error (RMSE) distributions were centered between 2.5 and 3.7 m while R2 distributions were centered between 0.4 and 0.7. The MISR/ GO aboveground biomass estimates predicted via regression on fractional cover and mean canopy height for the CLPX sites showed good agreement with U.S. Forest Service Interior West map data (adjusted R2=0.84). The implication is that multiangle sensors such as MISR can provide spatially contiguous retrievals of forest canopy height, cover, and aboveground woody biomass that are potentially useful in mapping distributions of aboveground carbon stocks, tracking disturbance, and in initializing, constraining, and validating ecosystem models. This is important because the MISR record is spatially comprehensive and extends back to the year 2000 and the launch of the NASA Earth Observing System (EOS) Terra satellite; it might thus provide a ~10-year baseline record that would enhance exploitation of data from the NASA Deformation, Ecosystem Structure and Dynamics of Ice (DESDynI) mission, as well as furthering realization of synergies with active instruments